EEEGM - ETHYL SULFIDE
- MSDS: EEEGM
- Manufacturer: MATHESON TRI GAS INC
- Product Name: ETHYL SULFIDE
- National Stock Number: -
Product Identification
Product ID:ETHYL SULFIDE
MSDS Date:Jan 24 1989
MSDS Number: EEEGM
Kit Part:=== Responsible Party ===
Company Name:MATHESON TRI-GAS, INC.
Address:959 ROUTE 46 EAST
City:PARSIPPANY
State:NJ
ZIP:07054-0624
Country:US
Info Phone Num:(USA) 973-257-1100, (WHITBY) 905-668-3570, (EDMONTON)
780-471-4036
Chemtrec Ind/Phone:18004249300
Contractor
Telephone: (USA) 973-257-1100, (WHITBY) 905-668-3570, (EDMONTON)
Ingredients
ETHYL SULFIDE
CAS: 352-93-2
Fraction By Weight: 100.0%
Hazards
Reports of Carcinogenicity:NTP:No IARC:No OSHA:No
Health Hazards Acute and Chronic:INHALATION: SHORT TERM EXPOSURE: no
information on significant adverse effects LONG TERM EXPOSURE: no
information is available SKIN CONTACT: SHORT TERM EXPOSURE:
irritation LONG TERM EXPOSURE: same as effects reported in short
term exposure EYE CONTACT: SHORT TERM EXPOSURE: irritation LONG
TERM EXPOSURE: same as effects reported in short term exposure
INGESTION: SHORT TERM EXPOSURE: no information on significant
adverse effects LONG TERM EXPOSURE: no information is available
Medical Cond Aggravated by Exposure:
First Aid
First Aid: INHALATION: If adverse effects occur, remove to
uncontaminated area. Give artificial respiration if not breathing.
Get immediate medical attention. SKIN CONTACT: Wash skin with soap
and water for at least 15 minutes while removing contaminated
clothing and shoes. Get medical attention, if needed. Thoroughly
clean and dry contaminated clothing and shoes before reuse. EYE
CONTACT: Flush eyes with plenty of water for at least 15 minutes.
Then get immediate medical attention. INGESTION: If a large amount
is swallowed, get medical attention.
Fire Fighting
Flash Point:16 F (-9 C)
Extinguishing Media:alcohol resistant foam, carbon dioxide, regular dry
chemical, water Large fires: Use alcohol-resistant foam or flood
with fine water spray.
Fire Fighting Procedures:Move container from fire area if it can be
done without risk. Dike for later disposal. Do not scatter spilled
material with high-pressure water streams. Cool containers with
water spray until well after the fire is out. Stay away from the
ends of tanks. Withdraw immediately in case of rising sound from
venting safety device or any discoloration of tanks due to fire.
For tank, rail car or tank truck, evacuation radius: 800 meters
(1/2 mile). Do not attempt to extinguish fire unless flow of
material can be stopped first. Flood with fine water spray. Do not
scatter spilled material with high-pressure water streams. Cool
containers with water spray until well after the fire is out. Apply
water from a protected location or from a safe distance. Avoid
inhalation of material or combustion by-products. Stay upwind and
keep out of low areas.
Unusual Fire/Explosion Hazard:Severe fire hazard.
Accidental Release
Spill Release Procedures:Avoid heat, flames, sparks and other sources
of ignition. Do not touch spilled material. Stop leak if possible
without personal risk. Reduce vapors with water spray. Small
spills: Absorb with sand or other non-combustible material. Collect
spilled material in appropriate container for disposal. Large
spills: Dike for later disposal. Remove sources of ignition. Keep
unnecessary people away, isolate hazard area and deny entry.
Neutralizing Agent:
Handling
Handling and Storage Precautions:Store and handle in accordance with
all current regulations and standards.
Other Precautions:
Exposure Controls
Respiratory Protection:Under conditions of frequent use or heavy
exposure, respiratory protection may be needed. Respiratory
protection is ranked in order from minimum to maximum. Consider
warning properties before use. Any supplied-air respirator with a
full facepiece that is operated in a pressure-demand or other
positive-pressure mode. Any self-contained breathing apparatus that
has a full facepiece and is operated in a pressure-demand or other
positive-pressure mode.
Ventilation:Based on available information, additional ventilation is
not required. Ensure compliance with applicable exposure limits.
Protective Gloves:Wear appropriate chemical resistant gloves.
Eye Protection:Wear splash resistant safety goggles. Provide an
emergency eye wash fountain and quick drench shower in the
immediate work area.
Other Protective Equipment:Wear appropriate chemical resistant
clothing.
Supplemental Safety and Health
ETHYL SULFIDE: No occupational exposure limits established.
Chemical Properties
Boiling Pt:194 F (90 C)
Melt/Freeze Pt:-148 F (-100 C)
Vapor Pres:Not available
Vapor Density:3.11
Spec Gravity:0.837
pH:Not available
Evaporation Rate & Reference:Not available
Solubility in Water:insoluble
Appearance and Odor:PHYSICAL STATE:liquid COLOR:colorless PHYSICAL
FORM:volatile liquid TEXTURE:oily ODOR:garlic odor
Corrosion Rate:
Stability
Stability Indicator/Materials to Avoid:Contact with water or moist air
may form flammable and/or toxic gases or vapors.
Stability Condition to Avoid:Avoid heat, flames, sparks and other
sources of ignition. Minimize contact with material. Avoid
inhalation of material or combustion by-products. Keep out of water
supplies and sewers.
Hazardous Decomposition Products:Thermal decomposition products:
hydrogen sulfide Thermal decomposition products: hydrogen sulfide
Conditions to Avoid Polymerization:Will not polymerize.
Disposal
Waste Disposal Methods:Dispose in accordance with all applicable
regulations.
Toxicology
Toxicological Information:ETHYL SULFIDE: IRRITATION DATA: 20 mg/24
hour(s) skin-rabbit moderate; 500 mg/24 hour(s) eyes-rabbit mild
LOCAL EFFECTS: Irritant: skin, eye
Other Information
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ecology
Ecological:Not available
Transport
Transport Information:U.S. DOT 49 CFR 172.101: PROPER SHIPPING NAME:
Diethyl sulfide ID NUMBER: UN2375 HAZARD CLASS OR DIVISION: 3
PACKING GROUP: II LABELING REQUIREMENTS: Flammable liquid
Regulatory
SARA Title III Information: SARA TITLE III SECTION 302 EXTREMELY
HAZARDOUS SUBSTANCES (40 CFR 355.30): Not regulated. SARA TITLE
III SECTION 304 EXTREMELY HAZARDOUS SUBSTANCES (40 CFR 355.40): Not
regulated. SARA TITLE III SARA SECTIONS 311/312 HAZARDOUS
CATEGORIES (40 CFR 370.21): ACUTE: Yes CHRONIC: No FIRE: Yes
REACTIVE: Yes SUDDEN RELEASE: No SARA TITLE III SECTION 313 (40
CFR 372.65): Not regulated.
Federal Regulatory Information:CERCLA SECTIONS 102a/103 HAZARDOUS
SUBSTANCES (40 CFR 302.4): Not regulated. OSHA PROCESS SAFETY
(29CFR1910.119): Not regulated.
State Regulatory Information: California Proposition 65: Not regulated.